# Eternal Battle mode

Win Saint Legend mode to unlock Eternal Battle mode.
# Lightning mode

Win Saint Legend mode to unlock Lightning mode.
# Saint Legend mode

Win The Hades mode to unlock Saint Legend mode.
# Aiacos

Follow Aiacos in The Hades mode to unlock Aiacos.
# Aiolia

Follow Aiolia in Story mode to unlock Aiolia.
# Aiolos

Win twenty battles in Eternal Battle mode to unlock Aiolos.
# Aldebaran

Follow Aldebaran in Story mode to unlock Aldebaran.
# Aqurius Hyoga

Defeat Aqurius Hyoga in Saint Legend mode to unlock Aqurius Hyoga.
# Dohko

Follow Dohko in Story mode to unlock Dohko.
# Final Cloth Hyoga

Defeat Rhadamanthys with Seiya in The Hades mode to unlock Final Cloth Hyoga.
# Final Cloth Ikki

Defeat Rhadamanthys with Seiya in The Hades mode to unlock Final Cloth Ikki.
# Final Cloth Seiya

Defeat Rhadamanthys with Seiya in The Hades mode to unlock Final Cloth Seiya.
# Final Cloth Shiryu

Defeat Rhadamanthys with Seiya in The Hades mode to unlock Final Cloth Shiryu.
# Final Cloth Shun

Defeat Rhadamanthys with Seiya in The Hades mode to unlock Final Cloth Shun.
# First Cloth Seiya

Win Lightning Battle mode with Seiya with at least 5 minutes to unlock First Cloth Seiya.
# First Cloth Shiryu

Won Lighttining Battle mode with Seiya with at least 5 minutes to unlock First Cloth Shiryu.
# Geminisaint

Follow Geminisaint in Story mode to unlock Geminisaint.
# Gold Aphrodite

Defeat Saint Legend mode with (Surplies) Aphrodite to unlock Gold Aphrodite.
# Gold Camus

Defeat Saint Legend mode with (Surplies) Camus to unlock Gold Camus.
# Gold Cloth Hyoga

Successfully complete Saint Legend mode with Hyoga to unlock Gold Cloth Hyoga.
# Gold Cloth Ikki

Successfully complete Saint Legend mode with Ikki to unlock Gold Cloth Ikki.
# Gold Cloth Seiya

Successfully complete Saint Legend mode with Seiya to unlock Gold Cloth Seiya.
# Gold Cloth Shiryu

Successfully complete Saint Legend mode with Shiryu to unlock Gold Cloth Shiryu.
# Gold Cloth Shun

Successfully complete Saint Legend mode with Shun to unlock Gold Cloth Shun.
# Gold Mepisto

Defeat Saint Legend mode with (Surplies) Mepisto to unlock Gold Mepisto.
# Gold Saga

Defeat Saint Legend mode with (Surplies) Saga to unlock Gold Saga.
# Gold Shura

Defeat Saint Legend mode with (Surplies) Shura to unlock Gold Shura.
# Libra Shiryu

Defeat Libra Shiryu in Saint Legend mode to unlock Libra Shiryu.
# Marin

Win five battles in Eternal Battle mode to unlock Marin.
# Milo

Follow Milo in Story mode to unlock Milo.
# Minos

Follow Minos in The Hades mode to unlock Minos.
# Mu

Follow Mu in Story mode to unlock Mu.
# Orpheus

Defeat Orpheus with Seiya in The Hades mode to unlock Orpheus.
# Rhadamanthys

Defeat Radamanthys with Mu in The Hades mode to unlock Rhadamanthys.
# Sagittarius Seiya

Defeat Sagittarius Seiya in Saint Legend mode to unlock Sagittarius Seiya.
# Shaina

Win ten battles in Eternal Battle mode to unlock Shaina.
# Shaka

Follow Shaka in Story mode to unlock Shaka.
# Shion

Defeat Shion with Shiryu in The Hades mode to unlock Shion.
# (Surprise) Aphrodite

Defeat Mepisto with Mu in Story mode to unlock (Surprise) Aphrodite.
# (Surprise) Camus

Defeat Mepisto with Mu in Story mode to unlock (Surprise) Camus.
# (Surprise) Mepisto

Defeat Mepisto with Seiya in Story mode to unlock (Surprise) Mepisto.
# (Surprise) Saga

Defeat Mepisto with Mu in Story mode to unlock (Surprise) Saga.
# (Surprise) Shura

Defeat Mepisto with Mu in Story mode to unlock (Surprise) Shura.
# 3D character models

Successfully complete ten rounds of Eternal Battle mode with any character. That character's 3D model can now be viewd in Zodiac History mode.